Publication


2019

Gatlin, D.M., Karney, W.L., Abe, M., Ault, B.S., Gudmundsdottir, A.D.

Formation and Reactivity of Triplet Vinylnitrenes as a Function of Ring Size

(2019) Journal of Organic Chemistry, 84 (14), pp. 9215-9225.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85070117278&doi=10.1021%2facs.joc.9b01191&partnerID=40&md5=9f197d75c55d4229f32d29f843939db0

DOI: 10.1021/acs.joc.9b01191


Yamato, K., Sekiya, R., Abe, M., Haino, T.

Separation of Spectroscopically Uniform Nanographenes

(2019) Chemistry - An Asian Journal, 14 (10), pp. 1786-1791.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85059684593&doi=10.1002%2fasia.201801632&partnerID=40&md5=8d838edacb3a052bd4eebd92ae999d79

DOI: 10.1002/asia.201801632


Yakiyama, Y., Wang, Y., Hatano, S., Abe, M., Sakurai, H.

Generation of "Sumanenylidene": A Ground-State Triplet Carbene on a Curved π-Conjugated Periphery

(2019) Chemistry - An Asian Journal, 14 (10), pp. 1844-1848.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061692746&doi=10.1002%2fasia.201801802&partnerID=40&md5=e1809a334c77646cf4b784d04f4702d9

DOI: 10.1002/asia.201801802


Yamada, A., Abe, M., Nishimura, Y., Ishizaka, S., Namba, M., Nakashima, T., Shimoji, K., Hattori, N.

Photochemical generation of the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radical from caged nitroxides by near-infrared two-photon irradiation and its cytocidal effect on lung cancer cells

(2019) Beilstein Journal of Organic Chemistry, 15, pp. 863-873.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85064229002&doi=10.3762%2fbjoc.15.84&partnerID=40&md5=4da22b38b4dec47ab736e5b3c551a1d4

DOI: 10.3762/bjoc.15.84


Yoshidomi, S., Abe, M.

1,2-Diazacyclopentane-3,5-diyl Diradicals: Electronic Structure and Reactivity

(2019) Journal of the American Chemical Society, 141 (9), pp. 3920-3933.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062334583&doi=10.1021%2fjacs.8b12254&partnerID=40&md5=8dacca5f8ea8c88e1e116cfc36664a02

DOI: 10.1021/jacs.8b12254


Matsumoto, M., Antol, I., Abe, M.

Curve Effect on Singlet Diradical Contribution in Kekulé-type Diradicals: A sensitive probe for quinoidal structure in curved π-conjugated molecules

(2019) Molecules, 24 (1), art. no. 209, .

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85059795466&doi=10.3390%2fmolecules24010209&partnerID=40&md5=8a707f34b9e503dbd9e6b6d8533ab1df

DOI: 10.3390/molecules24010209


Abe, M.

Generation of extremely long-lived localized singlet diradicals: New insights into bond-homolysis process and discovery of novel bonding system (C-π-C)

(2019) Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 77 (5), pp. 503-511.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85065963021&doi=10.5059%2fyukigoseikyokaishi.77.503&partnerID=40&md5=e9bdc8f178b887ba04a89de47a7de87d

DOI: 10.5059/yukigoseikyokaishi.77.503


Chitose, Y., Abe, M.

Design and synthesis of two-photon responsive chromophores for application to uncaging reactions

(2019) Photochemistry, 46, pp. 221-241.

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056574733&doi=10.1039%2f9781788013598-00219&partnerID=40&md5=178518b47bf9c62af120cc4b8d81bc34

DOI: 10.1039/9781788013598-00219


Shields, D.J., Sarkar, S.K., Sriyarathne, H.D.M., Brown, J.R., Wentrup, C., Abe, M., Gudmundsdottir, A.D.

Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures

(2019) Organic Letters, .

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85070557106&doi=10.1021%2facs.orglett.9b01950&partnerID=40&md5=deed475e9ea5b9829004da56ecc616b1

DOI: 10.1021/acs.orglett.9b01950


2018
Caged Compounds for Two-Photon Uncaging
Jakkampudi, S.; Abe, M.
in Elsevier Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2018, Chapter 13667.

Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic characterization, photoisomerization, and thermal decomposition
Yang, Y., Chu, X., Lu, Y., Abe, M., Zeng, X.
Molecules, 2018, 23 (12), art. no. 3312, 


Methoxyphosphinidene and Isomeric Methylphosphinidene Oxide
Chu, Xianxu; Yang, Yang; Lu, Bo; Wu, Zhuang; Qian, Weiyu; Song, Chao; Xu, Xinfang; Abe, Manabu; Zeng, Xiaoqing
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140(42) 13604-13608 Oct 2018


Extremely Long Lived Localized Singlet Diradicals in a Macrocyclic Structure: A Case Study on the Stretch Effect
Harada, Yuta; Wang, Zhe; Kumashiro, Shunsuke; Hatano, Sayaka; Abe, Manabu
CHEMISTRY-A EUROPEAN JOURNAL 24(55) 14808-14815 Oct 2018


Triplet States of Tetrazoles, Nitrenes, and Carbenes from Matrix Photolysis of Tetrazoles, and Phenylcyanamide as a Source of Phenylnitrene
Abe, Manabu; Begue, Didier; Silva, Hugo Santos; Dargelos, Alain; Wentrup, Curt
JOURNAL OF PHYSICAL CHEMISTRY A 122(37) 7276-7283 Sep 2018

Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer
Kamio, Shintaro; Kageyuki, Ikuo; Osaka, Itaru; Hatano, Sayaka; Abe, Manabu; Yoshida, Hiroto
CHEMICAL COMMUNICATIONS 54(67) 9290-9293 Aug 2018

Sulfamoyl nitrenes: singlet or triplet ground state?
Lu, Yan; Li, Hongmin; Abe, Manabu; Begue, Didier; Wan, Huabin; Deng, Guohai; Xu, Jian; Liu, Kun; Zeng, Xiaoqing
CHEMICAL COMMUNICATIONS 54(48) 6136-6139 Jun 2018

Selective Probing of Potassium Ion in Solution by Intramolecular Excimer Fluorescence of Dibenzo-Crown Ethers
Kida, Motoki; Kub, Mayuko; Ujihira, Tomoyuki; Ebata, Takayuki; Abe, Manabu; Inokuchi, Yoshiya
CHEMPHYSCHEM 19(11) 1331-1335 Jun 2018

Unusually Long-Wavelength Emissions of Cyclopropanes: New Insight into C-C Bond Homolysis
Abe, Manabu; Kanahara, Kousei; Kadowaki, Norito; Tan, Chun-Jui; Tsai, Hui-Hsu Gavin
CHEMISTRY-A EUROPEAN JOURNAL 24(30) 7595-7600 May 2018

Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole
Abe, Manabu; Begue, Didier; Santos-Silva, Hugo; Dargelos, Alain; Wentrup, Curt
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57(12) 3212-3216 Mar 2018

Experimental Observation of Thermally Excited Triplet States of Heavier Group 15 Element Centered Diradical Dianions
Fang, Yong; Zhang, Li; Cheng, Cheng; Zhao, Yue; Abe, Manabu; Tan, Gengwen; Wang, Xinping
CHEMISTRY-A EUROPEAN JOURNAL 24(13) 3156-3160 Mar 2018

Photochemically Induced Intramolecular Radical Cyclization Reactions with Imines
Lefebvre, Corentin; Michelin, Clement; Martzel, Thomas; Mvondo, Vaneck Djou'ou; Bulach, Veronique; Abe, Manabu; Hoffmann, Norbert
JOURNAL OF ORGANIC CHEMISTRY 83(4) 1867-1875 Feb 2018

Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene
Feng, Ruijuan; Lu, Yan; Deng, Guohai; Xu, Jian; Wu, Zhuang; Li, Hongmin; Liu, Qian; Kadowki, Norito; Abe, Manabu; Zeng, Xiaoqing
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140(1) 10-13 Jan 2018


Photochemical [2+2] cycloaddition reaction of enone derivatives with 2-siloxy-1H-pyrrole derivatives
Xue, Jianfei; Takagi, Ryukichi; Abe, Manabu
ARKIVOC 192-204 2018

2017
Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene
Wu, Zhuang; Feng, Ruijuan; Li, Hongmin; Xu, Jian; Deng, Guohai; Abe, Manabu; Begue, Didier; Liu, Kun; Zeng, Xiaoqing
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(49) 15672-15676 Dec 2017

Artocarmins G-M, Prenylated 4-Chromenones from the Stems of Artocarpus rigida and Their Tyrosinase Inhibitory Activities
Nguyen, Mai T. T.; Le, Tho H.; Nguyen, Hai X.; Dang, Phu H.; Do, Truong N. V.; Abe, Manabu; Takagi, Ryukichi; Nguyen, Nhan T.
JOURNAL OF NATURAL PRODUCTS 80(12) 3173-3179 Dec 2017

Contrasting Photolytic and Thermal Decomposition of Phenyl Azidoformate: The Curtius Rearrangement Versus Intramolecular C-H Amination
Wan, Huabin; Xu, Jian; Liu, Qian; Li, Hongmin; Lu, Yan; Abe, Manabu; Zeng, Xiaoqing
JOURNAL OF PHYSICAL CHEMISTRY A 121(45) 8604-8613 Nov 2017

Is π-Single Bonding (C-π-C) Possible? A Challenge in Organic Chemistry
Abe, Manabu; Akisaka, Rikuo
CHEMISTRY LETTERS 46(11) 1586-1592 Nov 2017

Two ring opened oxetane taxoids containing a C-20 benzoyloxy group from the roots of Taxus wallichiana Zucc.
Dang, Phu H.; Nguyen, Hanh H. T.; Truong, Hien T. T.; Do, Truong N. V.; Nguyen, Hai X.; Nguyen, Mai T. T.; Abe, Manabu; Takagi, Ryukichi; Nguyen, Nhan T.
TETRAHEDRON LETTERS 58(40) 3897-3900 Oct 2017

Laser flash photolysis of nanocrystalline alpha-azidop-methoxy-p-acetophenone
Sarkar, Sujan K.; Gatlin, DeVonna M.; Das, Anushree; Loftin, Breyinn; Krause, Jeanette A.; Abe, Manabu; Gudmundsdottir, Anna D.
ORGANIC & BIOMOLECULAR CHEMISTRY 15(35) 7380-7386 Sep 2017

N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene
Wan, Huabin; Li, Hongmin; Xu, Jian; Wu, Zhuang; Liu, Qifan; Chu, Xianxu; Abe, Manabu; Begue, Didier; Zeng, Xiaoqing
ORGANIC CHEMISTRY FRONTIERS 4(9) 1839-1848 Sep 2017

Computational study on 1,3-disilacyclobutane-1,3-diylidene disilylenes: A synthetic strategy for cis-bent disilenes
Fujita, Yoshiki; Abe, Manabu
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 30(9) Sep 2017

B(MIDA)-Containing Diborons
Yoshida, Hiroto; Seki, Michinari; Kageyuki, Ikuo; Osaka, Itaru; Hatano, Sayaka; Abe, Manabu
ACS OMEGA 2(9) 5911-5916 Sep 2017

Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions
Abe, Manabu; Chitosea, Youhei; Jakkampudi, Satish; Thuy, Pham Thi Thu; Lin, Qianghua; Van, Bui Thi; Yamada, Ayato; Oyama, Ryoko; Sasaki, Miyu; Katan, Claudine
SYNTHESIS-STUTTGART 49(15) 3337-3346 Aug 2017

Mechanistic study of stereoselectivity in azoalkane denitrogenations
Abe, Manabu; Hatano, Sayaka
PURE AND APPLIED CHEMISTRY 89(6) 759-764 Jun 2017

Design and Synthesis of a Caged Carboxylic Acid with a Donor-pi-Donor Coumarin Structure: One-photon and Two-photon Uncaging Reactions Using Visible and Near-Infrared Lights
Chitose, Youhei; Abe, Manabu; Furukawa, Ko; Ling, Jhe-Yi; Lin, Tzu-Chau; Katan, Claudine
ORGANIC LETTERS 19(10) 2622-2625 May 2017

Direct observation of methoxycarbonylnitrene
Li, Hongmin; Wu, Zhuang; Li, Dingqing; Wan, Huabin; Xu, Jian; Abe, Manabu; Zeng, Xiaoqing
CHEMICAL COMMUNICATIONS 53(35) 4783-4786 May 2017

Suplatast tosilate protects the lung against hyperoxic lung injury by scavenging hydroxyl radicals
Fukuhara, Kazuhide; Nakashima, Taku; Abe, Manabu; Masuda, Takeshi; Hamad, Hironobu; Iwarnoto, Hiroshi; Fujitaka, Kazunori; Kohno, Nobuoki; Hattori, Noboru
FREE RADICAL BIOLOGY AND MEDICINE 106 1-9 May 2017

Photolysis of 3,5-diphenylisoxazole in argon matrices
Sriyarathne, H. Dushanee M.; Sarkar, Sujan K.; Hatano, Sayaka; Abe, Manabu; Gudmundsdottir, Anna D.
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 30(4) Apr 2017

Paterno-Buchi photochemical [2+2] cycloaddition of aromatic carbonyl compounds with 2-siloxy-1H-pyrrole derivatives(dagger)
Xue, Jianfei; Abe, Manabu; Takagi, Ryukichi
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 30(4) Apr 2017


Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its sigma-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy
Yoshidomi, Shohei; Mishima, Megumi; Seyama, Shin; Abe, Manabu; Fujiwara, Yoshihisa; Ishibashi, Taka-aki
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(11) 2984-2988 Mar 2017

Control of the Termination Mechanism in Radical Polymerization by Viscosity: Selective Disproportionation in Viscous Media
Nakamura, Yasuyuki; Ogihara, Tasuku; Hatano, Sayaka; Abe, Manabu; Yamago, Shigeru
CHEMISTRY-A EUROPEAN JOURNAL 23(6) 1299-1305 Jan 2017

Light-harvesting organogel based on tris(phenylisoxazolyl)benzene
Ikeda, Toshiaki; Ueda, Yuko; Komori, Naomitsu; Abe, Manabu; Haino, Takeharu
SUPRAMOLECULAR CHEMISTRY 29(6) 471-476 2017

2016
The structure of electronically excited ,-unsaturated lactones
Freneau, Maxime; de Sainte-Claire, Pascal; Abe, Manabu; Hoffmann, Norbert
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 29(12) 718-724 Dec 2016


Using Molecular Architecture to Control the Reactivity of a Triplet Vinylnitrene
Sarkar, Sujan K.; Osisioma, Onyinye; Kamey, William L.; Abe, Manabu; Gudmundsdottir, Anna D.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138(45) 14905-14914 Nov 2016

Design, Synthesis, and Reaction of pi-Extended Coumarin-based New Caged Compounds with Two-photon Absorption Character in the Near-IR Region
Chitose, Youhei; Abe, Manabu; Furukawa, Ko; Katan, Claudine
CHEMISTRY LETTERS 45(10) 1186-1188 Oct 2016

Design and Synthesis of a 4-Nitrobromobenzene Derivative Bearing an Ethylene Glycol Tetraacetic Acid Unit for a New Generation of Caged Calcium Compounds with Two-Photon Absorption Properties in the Near-IR Region and Their Application in Vivo
Jakkampudi, Satish; Abe, Manabu; Komori, Naomitsu; Takagi, Ryukichi; Furukawa, Ko; Katan, Claudine; Sawada, Wakako; Takahashi, Noriko; Kasai, Haruo
ACS OMEGA 1(2) 193-201 Aug 2016

Impact of Diradical Spin State (Singlet vs Triplet) and Structure (Puckered vs Planar) on the Photodenitrogenation Stereoselectivity of 2,3-Diazabicyclo[2.2.1]heptanes
Abe, Manabu; Tada, Saori; Mizuno, Takemi; Yamasaki, Katsuyoshi
JOURNAL OF PHYSICAL CHEMISTRY B 120(29) 7217-7226 Jul 2016

Computational Study of Cyclobutane-1,3-diylidene Dicarbenes: Ground-State Spin Multiplicity and New Strategy toward the Synthesis of Bicyclo[1.1.0]but-1(3)-enes
Fujita, Yoshiki; Abe, Manabu; Shiota, Yoshihito; Suzuki, Tatsuya; Yoshizawa, Kazunari
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 89(7) 770-778 Jul 2016

Biphenalenylidene: Isolation and Characterization of the Reactive Intermediate on the Decomposition Pathway of Phenalenyl Radical
Uchida, Kazuyuki; Ito, Soichi; Nakano, Masayoshi; Abe, Manabu; Kubo, Takashi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138(7) 2399-2410 Feb 2016

A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis
Ye, Jianhuai; Hatano, Sayaka; Abe, Manabu; Kishi, Ryohei; Murata, Yusuke; Nakano, Masayoshi; Adam, Waldemar
CHEMISTRY-A EUROPEAN JOURNAL 22(7) 2299-2306 Feb 2016

Design and synthesis of a new chromophore, 2-(4-nitrophenyl)benzofuran, for two-photon uncaging using near-IR light
Komori, Naomitsu; Jakkampudi, Satish; Motoishi, Ryusei; Abe, Manabu; Kamada, Kenji; Furukawa, Ko; Katan, Claudine; Sawada, Wakako; Takahashi, Noriko; Kasai, Haruo; Xue, Bing; Kobayashi, Takayoshi
CHEMICAL COMMUNICATIONS 52(2) 331-334 2016

2015
Intra- and Intermolecular Reactivity of Triplet Sumanenetrione
Kanahara, Kousei; Badal, M. D. Mizanur Rahman; Hatano, Sayaka; Abe, Manabu; Higashibayashi, Shuhei; Takashina, Naoto; Sakurai, Hidehiro
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88(11) 1612-1617 Nov 2015

Multiple crystal forms of N,N '-diacetylchitobiose deacetylase from Pyrococcus furiosus
Nakamura, Tsutomu; Niiyama, Mayumi; Hashimoto, Wakana; Ida, Kurumi; Abe, Manabu; Morita, Junji; Uegaki, Koichi
ACTA CRYSTALLOGRAPHICA SECTION F-STRUCTURAL BIOLOGY COMMUNICATIONS 71 657-662 Jun 2015

Direct Detection of a Triplet Vinylnitrene, 1,4-Naphthoquinone-2-ylnitrene, in Solution and Cryogenic Matrices
Sarkar, Sujan K.; Sawai, Asako; Kanahara, Kousei; Wentrup, Curt; Abe, Manabu; Gudmundsdottir, Anna D.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137(12) 4207-4214 Apr 2015

Electron-spin resonance (ESR) characterization of quintet spin-state bis-nitroxide-bearing cyclopentane-1,3-diyl diradicals
Omokawa, Yasuyuki; Hatano, Sayaka; Abe, Manabu
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 116-120 Feb 2015

Photolysis of acetophenone derivatives with alpha-cyclopropyl substituents
Ranaweera, Ranaweera A. A. Upul; Weragoda, Geethika K.; Bain, John; Watanabe, Shinji; Abe, Manabu; Gudmundsdottir, Anna D.
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 137-146 Feb 2015

Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes
Fuku-en, Shin-ichi; Furukawa, Ko; Sasamori, Takahiro; Tokitoh, Norihiro; Abe, Manabu; Yamamoto, Yohsuke
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 79-87 Feb 2015


Unsaturated alpha-Ketoesters and Phenylglyoxal HydratesOrganocatalyzed Asymmetric Aldol Reactions of Ketones and beta,gamma-Unsaturated alpha-Ketoesters and Phenylglyoxal Hydrates
Konda, Swapna; Guo, Qun-Sheng; Abe, Manabu; Huang, Huicai; Arman, Hadi; Zhao, John C-G
JOURNAL OF ORGANIC CHEMISTRY 80(2) 806-815 Jan 2015

Formation of Isomerized E,Z-Configured 1,3-Dienes in Construction of Macrocyclic Trienes by Diene-Ene RCM
Takagi, Ryukichi; Tanaka, Kenji; Yamamoto, Koumei; Hiraga, Yoshikazu; Kojima, Satoshi; Abe, Manabu
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88(1) 146-148 Jan 2015

1,8-Disubstituted Xanthylidene-Based Remote Carbenes: Photolytic Generation and Isolation of Low-Coordinate Palladium(II) Complex
Sugawara, Shun; Abe, Manabu; Fujiwara, Yoshihisa; Wakioka, Masayuki; Ozawa, Fumiyuki; Yamamoto, Yohsuke
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (3) 534-541 Jan 2015

Simultaneous Observation of Triplet and Singlet Cyclopentane-1,3-diyl Diradicals in the Intersystem Crossing Process
Mizuno, Takemi; Abe, Manabu; Ikeda, Noriaki
AUSTRALIAN JOURNAL OF CHEMISTRY 68(11) 1700-1706 2015

Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes
Fuku-en, Shin-ichi;Furukawa, Ko;Sasamori, Takahiro;Tokitoh, Norihiro;Abe, Manabu;Yamamoto, Yohsuke
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 79-87 2015

Formation of Isomerized E,Z-Configured 1,3-Dienes in Construction of Macrocyclic Trienes by Diene-Ene RCM
Takagi Ryukichi;Tanaka Kenji;Yamamoto Koumei;Hiraga Yoshikazu;Kojima Satoshi;Abe Manabu
Bull. Chem. Soc. Jpn. 88(1) 146-148 2015

2014
Theoretical Study on Diradical Characters and Nonlinear Optical Properties of 1,3-Diradical Compounds
Kishi, Ryohei; Murata, Yusuke; Saito, Michika; Morita, Keisuke; Abe, Manabu; Nakano, Masayoshi
JOURNAL OF PHYSICAL CHEMISTRY A 118(45) 10837-10848 Nov 2014

Mode Switching of a Self-Propelled Camphor Disk Sensitive to the Photoisomerization of a Molecular Layer on Water
Nakata, Satoshi; Miyaji, Tatsuya; Matsuda, Yui; Yoshii, Miyu; Abe, Manabu
LANGMUIR 30(25) 7353-7357 Jul 2014

Time-Resolved IR Spectroscopy of 1,3-Dicyanophenylcyclopentane-1,3-diyl Diradicals: CN Stretching Wavenumber as a Vibrational Signature of Radical Character
Maeda, Akihiro; Oshita, Takahide; Abe, Manabu; Ishibashi, Taka-ak
JOURNAL OF PHYSICAL CHEMISTRY B 118(14) 3991-3997 Apr 2014

Scope and Limitation for FeSO4-Mediated Direct Arylation of Heteroarenes with Arylboronic Acids and Its Synthetic Applications
Komeyama, Kimihiro; Nagao, Yuya; Abe, Manabu; Takaki, Ken
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 87(2) 301-313 Feb 2014


Time-resolved IR spectroscopy of 1,3-dicyanophenylcyclopentane-1,3-diyl diradicals: CN stretching wavenumber as a vibrational signature of radical character.
Maeda Akihiro;Oshita Takahide;Abe Manabu;Ishibashi Taka-Aki


2013
Diradicals
Abe, Manabu
CHEMICAL REVIEWS 113(9) 7011-7088 Sep 2013

Kinetic Stabilization and Reactivity of Single-Bonded Species: Effect of the Alkoxy Group on the Lifetime of Singlet 2,2-Dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls
Nakagaki, Tomoyuki; Sakai, Tomoko; Mizuta, Tsutomu; Fujiwara, Yoshihisa; Abe, Manabu
CHEMISTRY-A EUROPEAN JOURNAL 19(31) 10395-10404 Jul 2013

Substituent effect on the energy barrier for sigma-bond formation from pi-single-bonded species, singlet 2,2-dialkoxycyclopentane-1,3-diyls
Ye, Jianhuai; Fujiwara, Yoshihisa; Abe, Manabu
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 9 925-933 May 2013

Substituent Effect on Reactivity of Triplet Excited State of 2,3-Diazabicyclo[2.2.1]hept-2-enes, DBH Derivatives: alpha C-N Bond Cleavage versus beta C-C Bond Cleavage
Abe, Manabu; Watanabe, Shinji; Tamura, Hiroshi; Boinapally, Srikanth; Kanahara, Kousei; Fujiwara, Yoshihisa
JOURNAL OF ORGANIC CHEMISTRY 78(5) 1940-1948 Mar 2013

A novel non-metathetic behavior of Grubbs catalyst: Ruthenium-mediated intramolecular [3+2] cycloaddition of bis-1,3-dienes
Takagi, Ryukichi; Yamamoto, Koumei; Hiraga, Yoshikazu; Kojima, Satoshi; Abe, Manabu
JOURNAL OF ORGANOMETALLIC CHEMISTRY 72(3) 171-175 Jan 2013

On the decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid - oxidation of the enol intermediate by triplet oxygen
Riahi, Abdelkhalek; Muzart, Jacques; Abe, Manabu; Hoffmann, Norbert
NEW JOURNAL OF CHEMISTRY 37(8) 2245-2249 2013

2012
Stretch Effects Induced by Molecular Strain on Weakening sigma-Bonds: Molecular Design of Long-Lived Diradicals (Biradicals)
Abe, Manabu; Furunaga, Haruka; Ma, Dongxia; Gagliardi, Laura; Bodwell, Graham J.
JOURNAL OF ORGANIC CHEMISTRY 77(17) 7612-7619 Sep 2012

Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser
Abe, Manabu; Iwakura, Izumi; Yabushita, Atushi; Yagi, Shingo; Liu, Jun; Okamura, Kotaro; Kobayashi, Takayoshi
CHEMICAL PHYSICS LETTERS 527 79-83 Feb 2012

The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a pi-single bonded character
Abe, Manabu; Ye, Jianhuai; Mishima, Megumi
CHEMICAL SOCIETY REVIEWS 41(10) 3808-3820 2012

2011
Stereochemical deuterium-labeling study on the denitrogenation of 7,7-diethoxy-2,3-diazabicyclo[2.2.1]hept-2-ene
Yagi, Shingo; Hiraga, Yoshikazu; Takagi, Ryukichi; Abe, Manabu
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 24(10) 894-901 Oct 2011

Concentration and Temperature Dependency of Regio- and Stereoselectivity in a Photochemical [2+2] Cycloaddition Reaction (the Paterno Buchi Reaction): Origin of the Hydroxy-Group Directivity
Yabuno, Youhei; Hiraga, Yoshikazu; Takagi, Ryukichi; Abe, Manabu
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133(8) 2592-2604 Mar 2011

The cooperative effect of a hydroxyl and carboxyl group on the catalytic ability of novel beta-homoproline derivatives on direct asymmetric aldol reactions
Hiraga, Yoshikazu; Widianti, Triana; Kunishi, Tsuyoki; Abe, Manabu
TETRAHEDRON-ASYMMETRY 22(2) 226-237 Jan 2011

Formation of macrocyclic lactones in the Paternò-Büchi dimerization reaction.
Arimura Junya;Mizuta Tsutomu;Hiraga Yoshikazu;Abe Manabu
BULLETIN JOURNAL OF ORGANIC CHEMISTRY 7 265-269 2011

2010
Computational study on the cyclopropanation reaction of ylides generated from alpha-pyridiniumacetates
Matsumura, Shuji; Takagi, Ryukichi; Kojima, Satoshi; Ohkata, Katsuo; Abe, Manabu
HETEROCYCLES 81(11) 2479-2495 Nov 2010

Novel cyclic beta-aminophosphonate derivatives as efficient organocatalysts for the asymmetric Michael addition reactions of ketones to nitrostyrenes
Widianti, Triana; Hiraga, Yoshikazu; Kojima, Satoshi; Abe, Manabu
TETRAHEDRON-ASYMMETRY 21(15) 1861-1868 Aug 2010

Computational study of the cooperative effects of nitrogen and silicon atoms on the singlet-triplet energy spacing in 1,3-diradicals and the reactivity of their singlet states
Nakamura, Takeshi; Gagliardi, Laura; Abe, Manabu
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 23(4) 300-307 Apr 2010

Generation and Intermolecular Trapping of 1,2-Diaza-4-silacyclopentane-3,5-diyls in the Denitrogenation of 2,3,5,6-Tetraaza-7-silabicyclo[2.2.1]hept-2-ene: An Experimental and Computational Study
Nakamura, Takeshi; Takegami, Akinobu; Abe, Manabu
JOURNAL OF ORGANIC CHEMISTRY 75(6) 1956-1960 Mar 2010

Stereoselective Triplet-Sensitised Radical Reactions of Furanone Derivatives
Jahjah, Rabih; Gassama, Abdoulaye; Bulach, Veronique; Suzuki, Chikako; Abe, Manabu; Hoffmann, Norbert; Martinez, Agathe; Nuzillard, Jean-Marc
CHEMISTRY-A EUROPEAN JOURNAL 16(11) 3341-3354 2010

Notable Substituent Effects on the Rate Constant of Thermal Denitrogenation of Cyclic Azoalkanes: Strong Evidence for a Stepwise Denitrogenation Mechanism
Ishihara, Chizuko; Abe, Manabu
AUSTRALIAN JOURNAL OF CHEMISTRY 63(12) 1615-1618 2010

2009
Stereoselective Wittig Reactions Using Pentacoordinated Phosphous Reagents
Arimura Junya;Kojima Satoshi;Abe Manabu
Abstracts of Symposium on Physical Organic Chemistry 2009(0) 267-267 2009

Substituent Effect at C2 position on the reactivity of singlet 1,3-diradicals
Nakagaki Tomoyuki;Sakai Tomoko;Fujiwara Yoshihisa;Abe Manabu
Abstracts of Symposium on Physical Organic Chemistry 2009(0) 277-277 2009


2008
Recent progress regarding regio-, site-, and stereoselective formation of oxetanes in Paterno-Buchi reactions.
Journal of the Chinese Chemical Society (Taipei, Taiwan) 55(3) 479-486 Sep 2008

Site- and stereoselectivity in the photochemical oxetane formation reaction (Paterno-Buchi reaction) of tetrahydrobenzofuranols with benzophenone: Hydroxy-directed diastereoselectivity?
Yabuno, Youhei; Hiraga, Yoshikazu; Abe, Manabu
CHEMISTRY LETTERS 37(8) 822-823 Aug 2008

Oxidation of archaeal peroxiredoxin involves a hypervalent sulfur intermediate.
Proceedings of the National Academy of Sciences of the United States of America 105(17) 6238-6242 Apr 2008

2007
Notable effect of an electron-withdrawing group at C3 on the selective formation of alkylidenecyclobutanes in the thermal denitrogenation of 4-spirocyclopropane-1-pyrazolines. Nonstatistical dynamics effects in the denitrogenation reactions
Hamaguchi, Masashi; Nakaishi, Masahiro; Nagai, Toshikazu; Nakamura, Takeshi; Abe, Manabu
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129(43) 12981-12988 Oct 2007

Exo-selective formation of bicyclic oxetanes in the photocycloaddition reaction of carbonyl compounds with vinylene carbonate: The important role of intermediary triplet diradicals in the stereoselectivity
Arkivoc (8) 58-65 Sep 2007
First Direct Detection of 2,3-Dimethyl-2,3-diphenylcyclopropanone.
Journal of Organic Chemistry 72(8) 2777-2784 Apr 2007

New development of reactive intermediate chemistry: a case study of singlet biradicals
Yuki Gosei Kagaku Kyokaishi 65(1) 16-22 Jan 2007

2006
An extremely long-lived singlet 4,4-dimethoxy-3,5-diphenylpyrazolidine-3,5-diyl derivative: a notable nitrogen-atom effect on intra- and intermolecular reactivity.
Angewandte Chemie, International Edition 45(46) 7828-7831 Oct 2006

Experimental Probe for Hyperconjugative Resonance Contribution in Stabilizing the Singlet State of 2,2-Dialkoxy-1,3-diyls: Regioselective 1,2-Oxygen Migration.
Journal of the American Chemical Society 128(24) 8008-8014 Jun 2006

A Matrix Isolation Study of 2-Isopropylidenecyclopentane-1,3-diyl (Berson-Type Diradical).
Journal of Organic Chemistry 71(17) 6607-6610 Apr 2006

Notable temperature effect on the stereoselectivity in the photochemical [2+2] cycloaddition reaction (Paterno-Buechi reaction) of 2,3-dihydrofuran-3-ol derivatives with benzophenone.
Tetrahedron Letters 47(15) 2527-2530 Mar 2006

2005
Alternative protocol for oxidation in water: an effective epoxidation system promoted by the combination of Oxone and an amphiphilic ketone.
Tetrahedron Letters 46(2) 213-216 Jan 2005

Novel Substituent Effects on the Mechanism of the Thermal Denitrogenation of 2,3-Diazabicyclo[2.2.1]hept-2-ene Derivatives, Stepwise versus Concerted.
Journal of the American Chemical Society 127(1) 10-11 Jan 2005

2004
Selectivity Control in Electron Spin Inversion Processes: Regio- and Stereochemistry of Paterno-Buechi Photocycloadditions as a Powerful Tool for Mapping Intersystem Crossing Processes.
Accounts of Chemical Research 37(12) 919-928 Dec 2004

Theoretical Calculations of the Effects of 2-Heavier Group 14 Element and Substituents on the Singlet-Triplet Energy Gap in Cyclopentane-1,3-diyls and Computational Prediction of the Reactivity of Singlet 2-Silacyclopentane-1,3-diyls.
Journal of Organic Chemistry 69(21) 7250-7255 May 2004

2-Silyl Group Effect on the Reactivity of Cyclopentane-1,3-diyls. Intramolecular Ring-Closure versus Silyl Migration.
Journal of Organic Chemistry 69(17) 5622-5626 Apr 2004

Mechanism of Stereo- and Regioselectivity in the Paterno-Buechi Reaction of Furan Derivatives with Aromatic Carbonyl Compounds: Importance of the Conformational Distribution in the Intermediary Triplet 1,4-Diradicals.
Journal of the American Chemical Society 126(9) 2838-2846 Mar 2004

Effects of Spiroconjugation on the Calculated Singlet-Triplet Energy Gap in 2,2-Dialkoxycyclopentane-1,3-diyls and on the Experimental Electronic Absorption Spectra of Singlet 1,3-Diphenyl Derivatives. Assignment of the Lowest-Energy ElectronicTransition
Journal of the American Chemical Society 126(2) 574-582 Jan 2004

2003
DFT Calculations on the Effects of Para Substituents on the Energy Differences between Singlet and Triplet States of 2,2-Difluoro-1,3-diphenylcyclopentane-1,3-diyls.
Journal of the American Chemical Society 125(42) 12823-12828 Oct 2003

Synthesis of Antimalarial Yingzhaosu A Analogues by the Peroxidation of Dienes with Co(II)/O2/Et3SiH.
Journal of Organic Chemistry 68(19) 7361-7367 May 2003

DFT Prediction of Ground-State Spin Multiplicity of Cyclobutane-1,3-diyls: Notable Effects of Two Sets of Through-Bond Interactions.
Journal of Organic Chemistry 68(4) 1618-1621 Feb 2003

Mechanism of an Alcohol-Trapping Reaction in the Direct and Benzophenone-Sensitized Photodenitrogenation of a Spiroepoxy-Substituted Azoalkane: Solvent Effects and Stereochemical Deuterium Labeling.
Journal of Organic Chemistry 68(5) 1796-1803 Feb 2003

2002
Reaction of 7,7-diphenyl-6-oxabicyclo[3.2.0]hept-1-ene with ROH; controlling factors on the regioselectivity in the nucleophilic addition reaction.
Tetrahedron 58(35) 7043-7047 Sep 2002


On the Electronic Character of Localized Singlet 2,2-Dimethoxycyclopentane-1,3-diyl Diradicals: Substituent Effects on the Lifetime.
Journal of the American Chemical Society 124(23) 6540-6541 Jun 2002

Multifunctional anti-angiogenic activity of the cyclic peroxide ANO-2 with antitumor activity.
International Journal of Cancer 100(2) 220-227 Feb 2002

Ozonolyses of 1-alkyl-substituted 1-tert-butylethylenes and highly methylated methylenecycloalkanes. The influence of the substituent steric bulk on the direction of cleavage of the primary ozonides.
Tetrahedron 58(5) 891-896 Feb 2002

2001
Paterno-Buchi [2+2] photocycloaddition reactions of silyl ketene acetals: Controlling factors on the regio- and stereoselectivity in the oxetane formations.
Yuki Gosei Kagaku Kyokaishi 59(9) 855-865 Sep 2001


Regioselective formation of 3-selanyl-3-siloxyoxetanes in the Paterno-Buchi reaction of silyl O,Se-ketene acetals (O,Se-SKA).
Synthesis (8) 1243-1247 Aug 2001

Regioselective Oxygenations of S-Trans Dienes, Silyl Dienol Ethers (SDEs), by Triphenyl Phosphite Ozonide (TPPO) and Its Mechanistic Study.
Journal of Organic Chemistry 66(10) 3548-3553 Mar 2001

New development of localized 1,3-biradicals. Oxygen atom effects on most stable spin multiplicity and reactivity.
Kagaku to Kogyo 54(2) 164-167 Feb 2001

2000
Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes.
Journal of the American Chemical Society 122(27) 6508-6509 Jul 2000


Paterno-Buechi Photocyclization of 2-Siloxyfurans and Carbonyl Compounds. Notable Substituent and Carbonyl (Aldehyde vs Ketone and Singlet- vs Triplet-Excited State) Effects on the Regioselectivity (Double-Bond Selection) in the Formation of Bicyclic exo-
Journal of Organic Chemistry 65(11) 3426-3431 Apr 2000

Notable Sulfur Atom Effects on the Regio- and Stereoselective Formation of Oxetanes in Paterno-Buechi Photocycloaddition of Aromatic Aldehydes with Silyl O,S-Ketene Acetals.
Journal of the American Chemical Society 122(17) 4005-4010 Apr 2000

Lewis acid promoted ring-opening reactions of 2-methoxy-2-siloxyoxetane in the presence of allylsilane: notable lewis acid effect on the ring-opening regioselectivity of the oxetane.
Main Group Metal Chemistry 23(11) 651-654 Mar 2000

Intramolecular and Intermolecular Reactivity of Localized Singlet Diradicals: The Exceedingly Long-Lived 2,2-Diethoxy-1,3-diphenylcyclopentane-1,3-diyl.
Journal of the American Chemical Society 122(9) 2019-2026 Mar 2000

Memory of chirality in photochemical reactions.
Kokagaku 31(1) 28-29 Jan 2000

1999
18O-Tracer Studies of Fe(II)-Induced Decomposition of 1,2,4-Trioxolanes (Ozonides) Derived from Cyclopentenes and Indenes. Inner-Sphere Electron Transfer Reduction of the Peroxide Linkage.
Journal of the American Chemical Society 121(28) 6556-6562 Oct 1999

Photooxygenation (Electron transfer) of silyl enol ethers derived from 1-indanone: silyl group and medium effects on the competitive formation of 3-siloxy-1,2-dioxetane and ? -peroxy ketone.
Main Group Metal Chemistry 22(9) 539-543 Sep 1999

Photooxygenation (1O2) of silyl enol ethers derived from indan-1-ones: competitive formation of tricyclic 3-siloxy-1,2-dioxetane and ? -silylperoxy ketone.
Journal of the Chemical Society, Perkin Transactions 1 (17) 2507-2512 Aug 1999

Donor-Acceptor Binary Photocatalysis System Illustrated by the Intramolecular Cyclization of a Cyclopropanone Acetal Tethered to Cyclohexen-2-one.
Bulletin of the Chemical Society of Japan 72(3) 511-517 Mar 1999

1998
Photochemical Generation and Methanol Trapping of Localized 1,3 and 1,4 Singlet Diradicals Derived from a Spiroepoxy-Substituted Cyclopentane-1,3-diyl.
Journal of the American Chemical Society 120(44) 11304-11310 Dec 1998

A stereoselective, tandem [2+2] photocycloaddition-hydrolysis route to aldol-type adducts.
Journal of the Chemical Society, Perkin Transactions 1 (19) 3261-3266 Sep 1998

Regioselective formation of 2-alkoxyoxetanes in the photoreaction of aromatic carbonyl compounds with β,β -dimethyl ketene silyl acetals: notable solvent and silyl group effects.
Journal of the Chemical Society, Perkin Transactions 1 (19) 3253-3260 Sep 1998

Electronic substituent effects on the EPR-spectral D parameter of trimethylenemethane (TMM) triplet diradicals compared with localized cyclopentane-1,3-diyls.
Journal of the Chemical Society, Perkin Transactions 2 (5) 1063-1068 May 1998

1997
Notable Substituent Electronic Effects on the Regioselectivity of an Oxygen-Atom Abstraction in the Reaction of Unsymmetrically Substituted Monocyclic 1,2-Dioxolanes with Triphenylphosphine.
Journal of Organic Chemistry 62(3) 752-754 Feb 1997

1996
Photoinduced electron transfer reactions of cyclopropanone acetal with conjugated enones in the presence of a redox-type photosensitizer.
Tetrahedron Letters 37(11) 1833-1836 Nov 1996

Selectivity in the ring-expansion and ring-switching reactions of bicyclooxonium ions.
Journal of the Chemical Society, Perkin Transactions 1 (5) 413-416 May 1996

1995
Oxidative Ring-Opening Reaction of Cyclopropanone Acetals with Carbonyl Compounds via Photoinduced Electron Transfer. Generation of a ? -Carbonyl Radical Species and Its Application to the Synthesis of ? -Hydroxy Ester Derivatives.
Journal of Organic Chemistry 60(10) 3065-3073 Mar 1995

1994
Electron Transfer Profile of Cyclopropanone Acetals in the Nonirradiated Reaction with Tetracyanoethylene, Chloranil, and Dicyanodichlorobenzoquinone.
Journal of Organic Chemistry 59(24) 7445-7452 Dec 1994

Formation of unsaturated esters in the single electron transfer reaction of cyclopropanone acetals with quinones under non-irradiation conditions.
Tetrahedron Letters 35(21) 3551-3554 Nov 1994


Photoinduced electron transfer reaction of cyclpropanone acetals with arylmethyl methanesulfonate: generation of β-keto radical species and application to C-C bond formation.
Journal of the Chemical Society, Chemical Communications (14) 1673-1674 Jul 1994

1992
Ring-opening addition reaction of cyclopropanol derivatives with carbenes.
Tetrahedron Letters 33(47) 7169-7172 Dec 1992

Bis(2-acetoxyacrylonitrile) and its phenylene and alkylene bis homologs. Preparation, isomerization, and intramolecular [2 + 2] photocycloaddition.
Journal of Organic Chemistry 57(8) 2263-2266 Apr 1992